Most of the coal, oil and natural gas produced in the world are used as fuels and a small part is used as a chemical feedstock. Undesulfurized coal and oil in the combustion process will produce a large number of sulfur oxides (SOx), serious harm to human health, and environmental damage. The unpurified natural gas containing hydrogen sulfide (H2S) is difficult for industrial application. This ...
WhatsApp: +86 18838072829In addition, the photocatalytic desulfurization process has little effect on the heat value of coal. On a basis of TGDSCDDSC analysis, it is found that the calorific value of the coal after photocatalytic desulfurization was slightly changed and the low temperature oxidation tendency was decreased which is helpful for desulfurized coal storage.
WhatsApp: +86 18838072829As a typical industrial byproduct during the flue gas desulfurization process of coalfired, flue gas desulfurization ash (FGDA) with alkali mineral can facilitate the water damage resistance of asphalt mixtures. However, low density and high hydrophilic coefficient of FGDA limit its improvement effect. Hence, the comprehensive moisture ...
WhatsApp: +86 18838072829At present, the desulfurization technology is divided into pretreatment, inuse treatment, and posttreatment. Inuse treatment, in the case of coal, is generally defined as the spraying of desulfurizer into the coalburning boiler, which is capable of converting SO 2 and SO 3 emissions from coal combustion into sulfites or sulfates (Lu et al. 1998; Sun et al. 2018).
WhatsApp: +86 18838072829In this work, the desulfurization process of highsulfur anthracite coal is discussed, and the desulfurization method of "reduced iron powder + heat treatment + magnetic separation" (named "RIHM") is designed. ... In this study, a highsulfur coal desulfurization experiment was carried out for highsulfur raw coal to reveal the internal ...
WhatsApp: +86 18838072829A process for coal desulfurization generates extremely low amounts of heat from microwave energy to induce thermochemical, insitu, reactions to liberate sulfur in the form of stable gaseous species, such as H/sub 2/S, COS and SO/sub 2/. Inventors:
WhatsApp: +86 18838072829Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The morphology and ...
WhatsApp: +86 18838072829environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. T his work summarizes the desulfur ization and denitration
WhatsApp: +86 18838072829The limestone gypsumbased wet desulfurization (WFGD) process is widely applied for flue gas desulfurization in coalfired power plants. However, enrichment of elemental chlorine in the desulfurization slurry would significantly impact the desulfurization efficiency, which requires regular discharge of desulfurization wastewater (He and Qi 2010).
WhatsApp: +86 18838072829Flue gas desulfurization (FGD) systems using lime or limestone as the chemical reagent are widely used throughout the world for SO 2 emissions control at coalfired power plants. Ammoniabased ...
WhatsApp: +86 188380728293. TYPES OF COAL Anthracite: This is the highest ranked, hardest, oldest, and least common type of possesses a high energy content, high percentage of carbon (>85%), energy content of 25 million BTU /ton (11,300 BTU/lb). Bituminous: This is the second rank of coal, softer and younger than anthracite, and containing a lower percentage of carbon (45 85%) and therefore more moisture and ...
WhatsApp: +86 18838072829article{osti_, title = {Coal desulfurization by a microwave process}, author = {Zavitsanos, P D and Golden, J A and Bleiler, K W and Jacobs, I S}, abstractNote = {A laboratory size flow reactor was developed and tested on coal samples up to 100 g/batch. A modified version of the applicator will increase sample size to 1000 g; when run continuously it can handle 500 g to 1000 g/minute.
WhatsApp: +86 18838072829The present work describes the desulfurization of coal using mildly reductive method. Both a Yanzhou and a Yanshan coal (referred to as YZ and YS coal, respectively), were treated in an aqueous media employing sodium borohydride (NaBH 4) as reducing agent, which is a well known hydrogen variables investigated include concentration of reductant, time, pH of initial media ...
WhatsApp: +86 18838072829Abstract. Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Due to its abundance, chemical and physical properties, FGDG has been used in several beneficial applications. However, during the past decade, the rate of beneficially used FGDG has ...
WhatsApp: +86 18838072829Coal desulfurization by microwave with additives has been investigated in many aspects, including desulfurization effects [38], coal property changes [39], sulfur species and dielectric characteristics [27,40]. ... XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave ...
WhatsApp: +86 18838072829Coal desulfurization The development and utilization of traditional coal plays a vital role in promoting social and economic development, but it has brought irreversible pollution to the ecological environment ( Zeng et al., 2021 ).
WhatsApp: +86 18838072829Fluegas desulfurization (FGD) material is a product of a process typically used for reducing SO 2 emissions from the exhaust gas system of a coalfired boiler. The physical nature of these materials varies from a wet sludge to a dry, powdered material depending on the process.
WhatsApp: +86 18838072829The complicated mass transfer during coke making process leads to the uneven spatial distribution of sulfur forms in coke, which is of great importance for the sulfur transformation and desulfurization efficiency. ... Char yield and desulfurization rate of YJH coal during pyrolysis. Fig. 5 presents the release rate of H 2 S, SO 2, ...
WhatsApp: +86 18838072829Sulfur dioxide is the most important precursor of acid rain and one of the major contaminants generated from coalfired power plants. Currently, the limestonegypsum wet fluegas desulfurization (WFGD) system is the most widely used method for removal of SO 2 from powerplant exhaust fumes. However, the gypsum byproduct of limestonegypsum WFGD ...
WhatsApp: +86 18838072829Coal desulfurization is imperative to create clean coal and reducing harmful emissions during the combustion process. However, organic sulfur in coal is more difficult to remove than inorganic sulfur. Therefore, in this paper, a method of coal sample desulfurization using citric acid with microwave assisted was proposed, and experimental ...
WhatsApp: +86 18838072829The main factor for the results above was that the desulfurization mechanisms were different. Therefore, the research of different desulfurization mechanisms is the main direction of future work. The consequence of this paper would provide data support for the selection of the desulfurization method for high sulfur coal.
WhatsApp: +86 18838072829In order to achieve better desulfurization effect, the researchers employ methods of adding chemical additives such as acid, alkali, oxidant, reductant, or changing the reaction atmosphere, or combining with other methods such as magnetic separation, ultrasonic and microorganism.
WhatsApp: +86 18838072829The FGD products are included in coal combustion products. The components of CCP's are as follows: fly ash, 57 percent; FGD products, 24 percent; bottom ash, 16 percent; and boiler slag, 3 percent. What is flue gas desulfurization? Flue gas desulfurization is a chemical process to remove sulfur oxides from the flue gas at coalburning powerplants.
WhatsApp: +86 18838072829For future approaches, as well as desulfurization process, increasing the purity of coal may also promote the value of coal and prevent environment pollution. In the study of Etemadifar et al., growing and resting cells of heterotrophic Rhodococcus erythropolis strains PD1, R1, and FMF, and R. qingshengii were utilized in sulfur removal and ...
WhatsApp: +86 18838072829The desulfurization process of circulating fluidized bed desulfurization technology involves the injection of flue gas from the bottom of the fluidized bed through a Venturi tube. ... Microwave heating motivated performance promotion and kinetic study of iron oxide sorbent for coal gas desulfurization. Fuel, 267 (2020), Article 117215, ...
WhatsApp: +86 18838072829When the consumed sulphur in coal is in the form of sulphur dioxide at the end of combustion, it reacts with water at high altitudes. Moreover, it goes down to the earth in the form of sulphuric acid, as well as damaging plants. The corrosive harmful impact on industrial plants is the removal of the sulphur in the coal when it is environmental.
WhatsApp: +86 18838072829Since the "Eleventh FiveYear Plan" period, the construction of flue gas desulfurization and denitrification facilities for coalfired power plants have been accelerated to control the emissions of sulfur dioxide (SO 2) and nitrogen oxides (NO X) and thus to address the issue of acid rain in to the goal of the "Thirteenth FiveYear Plan for Energy Saving and Emission ...
WhatsApp: +86 18838072829Desulfurization of Coal by Pyrolysis and Hydropyrolysis with Addition of KOH/NaOH Quanrun Liu, Haoquan Hu, Shengwei Zhu, Qiang Zhou, Wenying Li, Xianyong Wei, and Kechang Xie View Author Information Cite this: Energy Fuels 2005, 19, 4, Publication Date: April 23, 2005 https:////ef
WhatsApp: +86 18838072829Pyrolysis desulfurization is suitable for coal. By changing the coking conditions to promote the effusion of sulfide in the form of gas. ... The high temperature, pressure and strong acid or alkali in traditional desulfurization process increase the hazards and bring secondary pollution. Essentially, desulfurization is a combination of ...
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