The bauxite slurry typically has lower caustic concentration liquor as the bauxite is received with some humidity that acts to dilute the liquor which mixes with it at the start of the process. Thus, the step to single stream digestion not only provides an extra heat sink to improve energy efficiency, it also reduces the heater tube caustic ...
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Bayer process is about the production of alumina through the refining of aluminum ore (bauxite). The red mud is insoluble slurry waste that contains different types of oxides. Tremendous amount of this slurry is disposed every year (Marwaha et al., 2018 ).
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For the same grade of bauxite ore, using the traditional Bayer process, the theoretical maximum alumina dissolution rate is % and the Na 2 O mass fraction in the slag is about % (A/S = 1 and N/S = in the red mud), while the actual dissolution rate of the Bayer process bauxite ore in this alumina plant is about 70%, which shows ...
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In the Bayer process, the digestion temperature is an important factor in determining the alumina digestion rate. In this study, the digestion efficiency of the ore at different temperatures was investigated under the following conditions: caustic concentration 240 g/L, initial molar ratio, lime addition 15%, molar ratio of digested liquid ...
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• The purification of bauxite using Bayer's process. • The electrolytic reduction of anhydrous Al 2 O 3 by Hall and Herault's process. • The last step is the purification of impure aluminium by Hoope's process . In Baeyer's process, impure bauxite is converted into pure alumina. The conversion process involves mainly three reactions:
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The Bayer process is used for producing alumina (Al 2 O 3) from bauxite process was developed and patented by Karl Josef Bayer in 1887 [], which led to a dramatic reduction in the cost of aluminium process involves the following operations: mining, dissolution of the alumina at elevated temperatures, the addition of flocculants, precipitation of pure gibbsite, regeneration of ...
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As we go around the circuit, the aluminium concentration is decreased in the Precipitation (or crystallisation) step, and we end up with a "spent" liquor. This spent liquor (now poor in dissolved aluminium) completes the circuit to treat more bauxite. So the crux of the Bayer Process is dissolution of aluminium from its ore in the early part of
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The chemical and physical properties of bauxite residues are determined by the nature of the bauxite and the effect of the Bayer process. The technology and operating procedures at individual refineries ... together with a wide range of other oxides which will vary according to the country of origin of the bauxite. The high concentration of ...
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Alumina Production (Bayer Process) The aluminium production starts with the production of alumina from bauxite according to the socalled Bayer process. In the Bayer process, caustic soda (NaOH) is used to extract alumina from bauxite in digesters. High temperatures and pressures are required for this process (Kuenen et al. 2016).
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During the electrolysis process, the potential of the cathode relative to the reference electrode was measured as a function of the current at different concentrations of solid (100300 g L −1) and suspension temperatures (95120 °C).
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The Bayer process is used for refining bauxite to smelting grade alumina, the precursor to aluminum. Typically, depending upon the quality of the ore, between and tonnes of bauxite is required to produce 1 ton of alumina. The Bayer process involves the digestion of crushed bauxite in the concentrated sodium hydroxide (caustic) solution at
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It is well known that the Bayer process is the main method to extract alumina from the bauxite in the world [19]. However, Bayer process is only suitable for the treatment of high grade bauxite ore. With the development of alumina production capacity, the resources of high quality bauxite are decreasing year by year [10, 11].
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Bauxite residue is the byproduct of alumina production and is generated in the Bayer process when bauxite is digested in hot NaOH under elevated temperature and pressure. ... H 2 C 2 O 4 concentration, contact time and temperature had the most pronounced effect on the extracted Ga (ranging from to mg/kg while leaving the other factors ...
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Therefore, the aluminum concentration in the liquor is kept below the solubility limit, which is ensured by the high solidtoliquid ratios of 1/6 in case of Bayer process with bauxite residue and sintering and 1/10 in case of aluminaenriched slag leaching. Results and Discussion.
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Lime is an essential reagent required in various process steps of the Bayer process, in which bauxite ore is converted into alumina (Whittington et al. 1997), as illustrated in Fig. is used for improving conversion of goethite to hematite and dissolution of boehmite and diaspore during digestion; control of liquor impurities such as silica, oxalate, titanium and phosphorous; minimising ...
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The aim of this work was to achieve an understanding of the distribution of selected bauxite trace elements (gallium (Ga), vanadium (V), arsenic (As), chromium (Cr), rare earth elements (REEs), scandium (Sc)) in the Bayer process. The assessment was designed as a case study in an alumina plant in operation to provide an overview of the trace elements behaviour in an actual industrial setup.
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JOM The problem that sulfur causes in alumina production using the Bayer process can be eliminated by adding sodium nitrate, ... Padilla et al. reported that highsulfur bauxite generally refers to the usual bauxite with a sulfur concentration of more than %. 3 The main sulfur minerals in bauxite are pyrite (FeS 2) and its isoforms ...
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The Bayer process is the principal method for production of alumina from bauxite worldwide. The modern version of the process (developed in the 1880's) still maintains
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The alumina extraction and iron minerals' comprehensive utilization of technology that could replace the current Bayer process have not yet been formed. In the current Bayer digestion process, gibbsitic bauxite was digested at a temperature, alkali concentration, and time of 100150 °C, 120190 g/L, and 1090 min, respectively.
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The concentration of the Bauxite ore into alumina is done by Bayer's process. Alumina is then refined into pure aluminium metal through the HallHéroult electrolytic process. Aluminium is too high in the electrochemical series (reactivity series) to be extracted from its ore using carbon reduction.
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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 3060% aluminium oxide (Al 2 O 3 ), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
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Aluminum production from bauxite is achieved with the Bayer process, which is a hydrometallurgical method. However, in the Bayer process, in time, it is possible to encounter problems such as the formation of excessive amounts of red mud in aluminum production, its environmental risks, its requirement of large storage sites, the excessive production of reactants by ores with low silica modulus ...
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While some oxalate enters the Bayer process with bauxite as oxalic acid adsorbed on various minerals, the majority is created by the oxidation and pyrolysis of bauxite organics under Bayer digestion conditions. The rate of its formation in digestion is principally related to the bauxite organic carbon concentration and composition, and to the ...
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Bayer's method for the extraction of Alumina: ∙ Conversion of impure bauxite to sodium aluminate; Bauxite in the powdered form is added to conc. sodium hydroxide and then heated in a closed vessel at 433 K and 5−6 bar pressure for 6 −8 hours. The aluminium oxide in bauxite is converted to sodium aluminate which is soluble in water.
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Gardannes's Bayer Plant has been modified to process Boké bauxite with a double digestion. ... Bayer process. Higher concentration of spent liquor will bring about higher productivity in ...
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This paper proposes a novel approach to sulfur removal by adding aluminum in the bayer process of highsulfur bauxite. The effects of aluminum dosage on the concentrations of different valence sulfur in sodium aluminate solution were investigated at length to find that highvalence sulfur (S 2 O 3 2−, SO 3 2−, SO 4 2−) concentration in sodium aluminate solution decreases, but the ...
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3. concentration on silica concentration in the liquor at various residence time is shown below Caustic Concentration of Liquor Higher the caustic concentration faster will be the dissolution of reactive silica from bauxite in the liquor. But at the same time high concentration of caustic liquor will have a higher equilibrium concentration of the silica lowering the desilication rate. 2. ...
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Aluminium manufacture is accomplished in two phases: the Bayer process of refining bauxite ore to obtain aluminium oxide (which is carried out at AAL), and the HallHeroult process of smelting the ... The maximum concentration of alumina dissolved in the caustic, known as the ratio (as Al 2 O 3 /Na 2 CO 3), occurs in digestion, while the
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Fig. 2 illustrated the main process of extracting alumina from bauxite by Bayer process and the alkali sources of Bayer bauxite residue. Table 3, Table 4 summarized the main elements and mineralogical compositions of different types of bauxite, as well as the Bayer process parameters applicable to them (Ruys, 2019). It can be concluded that the ...
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temperature, retention time, free caustic concentration and molar ratio of solution. Based on the experimental data, the calculation models of raw material consumption for different bauxites were established. Under the same basic raw material price, lowtemperature Bayer process was suitable for treating Bauxite1 and Bauxite3.
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Bauxite Al 2 O 2 O; Corundum Al 2 O 3; Cryolite Na 3 AlF 6; Metallurgy of Aluminium. Aluminium is mostly extracted from its bauxite ore. Dressing of Ore. The ore is mechanically crushed and pulverized. Concentration of ore. The bauxite ore contains ferric oxide and silica as impurities.
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Bauxite is the major ore for aluminum production, and mainly consists of aluminum hydroxides and oxidehydroxides, iron oxides and oxidehydroxides, clay minerals, silicon dioxide and titanium dioxide, often in various polymorphic mineral phases. 7,8 The concentration of gallium in bauxite ranges from below 10 ppm to over 800 ppm, with an ...
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